Thanks for your post. Actually, there is currently another active thread with a very similar topic. Please take a look at https://community.icinga.com/t/i-need-to-upgrade-centos7-to-rhel-v9/13890.
Please don’t try to add another master node, as the master-master-replication only allows two nodes.
Please refer to the documentation’s backup section, as @log1c did in the mentioned thread above. The CA as well as other backup- or migration-worthy files should reside within /var/lib/icinga2
.